If you want to deploy the new OneDrive Next Generation Sync Client using SCCM, then there is a excellent guide available detailing how to do this over at scconfigmgr.com
You can see the guide by clicking the link below:
https://www.scconfigmgr.com/2016/05/24/deploy-onedrive-next-generation-sync-client-with-configmgr/
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