If you need to export your Exchange mailbox address details to CSV then you can run the following EMS PowerShell command to export the name, primary SMTP email address and the mailbox database where the mailbox is allocated.
Get-Recipient -Resultsize unlimited | select name, primarysmtpaddress, Database | export-csv C:tempaddresses.csv
You can change the file location to wherever you want to save the CSV file to.
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